Within the 75mm gap is rockwall fibre insulation.
I thought I will take out the rather useless insulation and put in 75mm sheets of Kingspan or something
Why? (IE why is it "rather useless" & why change it)
That sounds like a lot of work & cost for minimal gain.
What is the dif in values between the two products? I doubt at 75mm if the gain would be worth the cost / effort.