...... The air in my loft in summer is colder than the air in the house, because it's shielded from the sun.
On the temperature in the loft djh's post referenced above, are you sure ?
Yes, I'm sure. When it gets seriously too hot in the house, I open the loft hatch which cools the house down for a while. But for reasons lightfoot has explained, the cooling effect is one shot and takes until the next day to recover.
There's nothing magic about our roof but it does face east and west, which may make it behave differently to ones that face north and south. perhaps?