Hi All
Thanks for the info ..... the build-it-solar site has a number of updates since I last looked.
Baz correctly picked up that the idea would be to just use the area enclosed by the curtain wall to collect the heat and use a differential thermostat linked to an extractor to transfer heat into the house as and when heat becomes available, allowing the structural mass inside the existing insulating 'shell' to act as a thermal store. I too envisage using painted thin metal sheeting as an absorbing surface allowing both a higher temperature panel/air heat transfer and a faster warming cycle, although for a while I did consider a rigid ducting collector solution, however, I hadn't considered insulating the solid wall behind the collecting surface ..... the curtain wall would probably have to include a set of conservatory blinds to as well as some ventilation to prevent summer meltdown.
The Curtain wall would probably be built from standard PVCu profiles (dark grey) and double glazed (apparently double glazed panels are actually cheaper than slightly thicker single glazing) as 'she who must be obeyed' insists that if it is built it 'must be asthetically pleasing' ..... whatever that means
Cheers ....
##Edit .... thanks dhaslam ... adjacent walls have windows, this is an existing 'blank' wall ....