So if say, 50Ah worth of brand new, fully charged batteries were used with the APC unit above, what would a rough estimate of the backup time, bearing in mind the combi seems to average about 140W when fired up?
As a very rough estimate, 50Ah x 24V is about 1200Wh. 1200/140 is about 8 1/2. That doesn't account for losses and conversion efficiency etc, but you are still looking at several hours - probably 4+, maybe even 6+. It's likely to be fairly high since you are discharging the batteries at quite a low rate - so you actually get a lot more out of them that you would if the load was larger.
I've also remembered another reason not to put large batteries on a UPS not designed for them - and it's to do with the recharge profile. A good UPS will have a 3 stage charge regime :
1) Bulk mode - the UPS supplies as much current as the charger can produce (constant current mode), and the battery absorbs it. This is the initial bulk charge and will provide around 80% of the stored energy (charge).
2) Absorption mode. When the battery voltage reaches a certain level, the charger switches to constant voltage mode and the charge current drops off as the battery fills up.
3) Float mode.When the charge current drops below a set current, the charge is complete and the charger will reduce it's output voltage - the battery is now being 'floated', it's not taking any additional charge in, the current going in is just correcting for the (small) amount of self discharge that happens in all batteries.
The problem is that with large batteries, the threshold current to switch from stage 2 to stage 3 may not be reached. At the higher charge voltage, once the charge is complete then the extra energy goes into splitting water into hydrogen and oxygen and the battery will always take some current. If the battery size and charger are very mismatched then it's possible that the residual current is higher than the switching threshold and the charger might never switch to float mode. Depending on conditions (hotter is worse), this may lead to batteries drying out - "dry cell" AGM batteries have an incredibly small quantity of water in them so they are easily killed by overcharging. Wet batteries would not be a problem since they can easily be topped up.
Hmm, it's not getting any simpler is it
