RenewableJohn,
Is that adding caustic to water (soda) as I have done some work for a plating plant and have seen a potentially horrible accident with someone adding caustic to a heated cleaning tank too quickly. He was ok after an emergency shower but it did cause a bit of a drama

I am not saying I am doing anything revolutionary but I have been thinking of matching a panel array to provide winter heat. Then in summer the waste stagnation temps would provide generation. Its a little frustrating as collector temps and required generation temps are so near but the small difference in terms of efficiency also makes them so far.
Saying that though I have found a few products that come very close and rear mounted parabolic mirrors might just give that extra umph required.
I have been looking at :-
CoolEnergyInc's Stirling product
http://www.coolenergyinc.com/Sunpowers Stirling products
http://www.sunpower.com/lib/sitefiles/pdf/productlit/Engine%20Brochure.pdfCyclonePowers Rotary
http://www.cyclonepower.com/PDF/WHE_Spec_Sheet.pdfFreePower.co.uk ORC solutions
http://www.thursbygarden.org/images/pdf/7_10.03.02_FP85_SpecDimension_Rev_2.pdf.PdfCompressor-194521.pdfThese all represent temps near to the max that you can get from a standard solar collector.
Your steam evaporator sounds a good idea and my thought path is not for microgeneration but for a term I call macrogeneration. Where small communities, districts can gain the benefits from economy of scale. Where maybe a supplier might be able to make a viable exchange for heat for FITs (roof space for heat). In the Burnley area we have a lot of terraces where the installation of linked panels to a centralised generation / heat distribution system would provide many mutual benefits. This would suit most high density urban schemes though. CHP is amazingly efficient for small scale heating distribution and electricity is easily fed back to the grid.
I have a bit of inheritance and I am holding fire at the moment as there seems to be various products getting near to the figures I require. It even occured to be to utilise the stirling out of the whispergen and baxi CHP units as mass production always makes huge dents in cost.
The macrogeneration term is about being scalable and in a community scheme a redundent array of generators could come online when the heat is available and shrink to extend the generation period to its maximum.
As I say, I am holding fire as I haven't found a direct flow evacuated tube that really hits the mark. Well the
http://srbenergy.com CERN product is perfect but it is stuck in the quagmire of the Spanish solar industry and cost. I do actually aim to setup a system at home and get my 20 years of automation skills utilised to provide concise data capture of the process.
If you think you have anything to add where the overall system will budget around £15,000 give a bit either way, then I would be most appreciative. Still fact finding and still searching the market but I am going to give it a go.