http://www.stoakes.co.uk/pages/rooflights/kalwall_nanogel_rooflights.htmThese are nanogel translucent sheets, very good U value but i'm sure far too expensive for an agricultural building.
Most often used is double skin glass fibre.
I take it that although you have planning permission there is a condition that materials have to be agreed?
Changing the shape of the roof will need a new application I would have thought?
I bet the planners would think a saw tooth roof "looks like a factory" whine, whine.
Now how about a green roof like the Adnams Brewery Distribution centre - interesting company Adnams - into all sorts of green tech, including I think bio digesters.
http://www.corusconstruction.com/file_source/StaticFiles/Construction/Panels_and_profiles/case_studies/Adnams%20Brewery%20CS.pdf