That using the FHZ1300 I can set multiple temperatures and times for each room thermostat (FHT80b)?
No I don't believe you can do this using the standard software that comes with the FHZ1300. It is basically a gui for programming the day/night temps and the timers in the FHT80bs. My version is about 2 years old and may have changed since then. I did download the latest version from elv to test, but it is in German.
Alternatively, you can ignore the elv software completely and use the open source FHEM. It is a bit fiddly to set up, but would give you the ability to create timed events on the PC running FHEM. The timed events can set any parameter on each FHT80b. For example, you could create timed events to set the "Current Desired Temperature" to be 21deg c at 7am, 18deg c at 9am etc.
This method does not use the inbuilt timers on the FHT80b. The PC runnig FHEM will need to be always switched on.
With the FHZ1300 can the boiler (well store pump actually) be controlled via a FS20 switch, or do I need the FHT8W boiler control?.
Yes, I believe that using FHEM you could create events that switch on the FS20 (connected to your pump or boiler) whenever the demand from any of the FHT80bs was > 1%. This replicates the function of the FHT8w in software. I did this for 2 years (using HomeSeer and network controlled relays). The downside is that you are reliant on the PC being on and FHEM working properly. If the PC stops working, or doesn't come back up after a power cut then your heating won't work.
For that reason, I have installed the FHT8W. In the event the PC has a problem, the heating can be controlled using the FHT80Bs directly. I still use the PC for monitoring and setpoint control, but the boiler control isn't reliant on it.
I would recommend getting an FHZ1300, and maybe an FS20, if you intend to increase the number of FHT80bs you have. It is much easier to view and change all the set points and timers for all your FHT80bs from one PC, rather than running around the house fiddling with each room thermostat. You can always add the FHT8W at a later date. Remember the FHT8W will only listen to a maximum of 10 FHT80 devices.
If you wanted to compromise slightly on the level of control, you could combine the FHT80bs with a normal 7 day central heating timer. eg, set the day/night setpoints on the FHTs to say 25 and 21, and then only switch on the heating using the timer a couple of times a day.