Paddylen emailed me on this and we had several email exchanges prior placing it on the Forum for all to ponder. Unfortunately the drain-down version of the DPS Panndora (rather than the version with solar coil) complicates the control and heat transfer options.
Paddy - ignore my comments re evacuated tube panesl not being suited to drain-down systems. I overlooked the inclusion of a solar Heat Exchanger which allows the solar loops to run full of water continuously - sorry! You new drawing makes everything clear on what is a dull wet day

My suggestion was to operate the Heat Exchanger pump in parallel with the solar pump. However doing this as a direct connection will result in the Store reverse-heating the Heat Exchanger (and solar loop) in winter when the initial Store temp is higher than the solar loop temp = unwanted loss of fossil heated energy.
Therefore an additional thermostat could be connected in series with the HE pump which only allows the HE pump to run when the HE is at 25 deg C (for example). This will prevent the HE pump running until the solar loop has pre-heated the HE, thus preventing the HE being used to pre-heat the solar loop during initial morning runs in winter.
However on further thoughts, this will prevent the anti-freeze CFR controller function being effective becasue the HE won't have the thermal mass to store heat without re-heating from the Store. Hence it would be essential to have antifreeze in the system.
I cannot see any other way to get the ES controller to operate the exchange pump via a separate relay.
Antman