I meant i terms of diverting flow between two coils, ...
Not sure you can do that with a TMV in reverse.
What is your heat source for that ? From what I've read, many solar controllers have an output that can be used to drive a diverter valve.
The problem I see is that with solar, as the sun comes out you will have low grade heat - you can put that through a lower coil to heat the store bottom up but then the loop temperature will stay cool and you'll not get to switch to top loading via the upper coil. Alternatively, you keep keep the pump turned off (or slow it down if variable speed) to allow the loop temperature to climb so that you can top load your store through the upper coil.
You'd need a thermostat/temperature sensor half way up the store to control the system with as well.
The method I described is for use with a boiler etc - and prevents you pumping cool water into the top of a previously stratified store - thus killing the stratification. It will prevent flow into the store until the supply is hot, and thereafter would regulate the flow temperature (by indirectly controlling the temperature of the water going into the heat source) if the heat source was unable to maintain output temperature at full flow rate and available input temperature.