should I fill the kettle from the hot water tap
I've been wondering whether it makes sense to go even further. If the thermal store is run hot, there'll probably be a TMV between the thermal store and the hot tap, so maybe it would pay to have a separate Very Hot Water tap for filling the kettle, like those very expensive 'butler taps' some makers offer. I guess the question would be how much water cools in the pipe between uses.