I like the idea of a 12-24V (some said 42V some said 48V) bus.
http://www.navitron.org.uk/forum/index.php/topic,2527.0.htmlThere was a poll on this, but I can't find it now.
Take the time to consider what components you would need if you had no mains. Which areas would you consider for LED 'Emergency lighting'? Cos that might well be the best approach to use.
It might be sensible to bring 2.5mm twin and earth back to a central point, and if you are to have a central point where would it be? That way you can control your system from one location rather than distributed switches.
That way you can start to play with the system with a directly beneficial element. That central point would seem to be a sensible place to locate batteries or if you feel a mains infrastructure is more suitable then that can be implemented as a fail over as well as the existing house lighting. But please remember a 240 Volt infrastructure like this would require proper PArt P certification and as it is separately sourced then there are complications.
The objective is to move from one traditional 240 Volt system to a hybrid where,upon consideration you can turn off 240 Volt components was you come to turns with what you might require out of the standby system.
How you control the system becomes an important area of consideration but I wouldn't think it could be really properly considered until you've seen the low voltage system in context. Is it bright enough to provide safe movement in all areas of the house.
Switching might initially seem to be a lacking element but rather than go to all the domestic upheaval of wiring a separate switch system with all the confusion if you use anything like the same style of switch, you might start to consider motion sensors as a suitable mechansim for switching your new system. The control of such in the low voltage world is at best dedicated and as such you are likely to be constructing certain elements yourself.
If you lay a screened twin pair of signal cable along with the 2.5mm twin and earth then perhaps you could consider some degree of centralized control. ( He's going to say one-wire isn't he?) using something like one-wire. That way you could ( I don'd know of a specific PIR to one wire but i'm sure your new found skills would welcome that as a project component that will certainly get you considering some of the characteristics of such systems) take control with a once only visit for installation.
If I can't find my voltage poll I should be able to get by without being reminded of my 'Don't use one wire for control' post, but you should be able to get a low voltage system to be fairly noise immune, especially if part of your system design means it works when there isn't any mains. Thats probably a fairly cost effective solution. It also protects you from all the complexities of switching off the various mains devices that you might consider important when you have mains but less so when you don't.
What you will lack is standard components for this sort of thing. A trip to a proper truck stop will demonstrate a bewildering range of devices for 12 and 24 volt infrastructure and that probably a fair bit cheaper than approaching the sailing community, which tends to have a leisure based price tag attached. Personally I think it's going to be 42 Volts as cars are going to that voltage so components should get cheap, but thats just my view.
The excellent part of your approach is you are using the system to perform both a useful energy project as well as an excellent teaching toll.
Please tell us how you get on.