KLD,
Thanks for the tips - as you can see from the photos, the day was anything but cloudy so that may have had a bearing on why I've struggled!
The friction seemed worst at the point where the glass tube met the rubber boot. I just wetted the glass and pushed it in with a twisting movement once the copper bulb was lined up in the manifold. I also had a couple of manifold ports which were out of alignment with the bulb sockets - in the end, I had to remove the rubber boots from the port, place it over the tube and then re-insert, boot and all.
I'll let you know how I solve the venting/air lock problem once I've finished bleeding the system

In theory... the horizontal pipe terminates in a tee-piece. There is a ball valve and rad valve on the upward facing branch of the tee, the lower branch is flow or return as this arrangement has been put in at both ends of the manifold. Sounds good in theory...
... In practice... I struggled to get the system to circulate yesterday until I bled some of the glycol mix at the thermal store which cleared an air lock and got the flow from the manifold to the store working (or so I thought). Today, we had a decent amount of sun and the system appeared to be working for a while, but a climbing manifold temp and only slowly increasing store temp had me worried. The flow to the store was hot but the return was cold. What's more, the return was pretty warm in the attic as well - so it appeared that the manifold was stagnating. Sure enough, cracking the bleed valves got me a whole load of steam out of the manifold flow which allowed more glycol mix into the manifold - and then the sun went in... but I got the manifold temp reading down from 77c to about 55c in the time it took me to get out of the attic. There is clearly an art to bleeding these systems - I guess the use of long runs of 10mm pipe (approx 25m in total) doesn't make it any easier.
So far, even with my incompetence over the last 2 days, the top of store temp has risen from 32c to 45c. (It's an Akvaterm solar 500 with a notional 500 litre capacity but it's baffled to split 300 litres solar, 200 litres direct heat).
Off to re-pressurise and re-bleed...
50 tuba