Ken,
A thermostatic mixing valve at the tank outlet is certainly a very good idea. Your solar panels can then heat the tank during summer to higher temperatures, say 85°C, and that way you can store more heat for the subsequent two dull days. If you the were to feed 85°C hot water towards the taps

. On the downside, the TMV will always mix-in some cold water, even when the store supplies water below the set temperature. This is to allow for the safety shut-off in case of cold mains failure. Whether thermostatic shower mixer are the same in this respect, I dunno.
So, in short, if you install a TMV on the tank outlet and set that to, say, 45°C. then you could do away with the thermostatic shower mixer. The TMVs are available in larger DN, so you don't loose too much flow.
Klaus