Why is the boiler running all the time? Shouldn't it be off for at least part of the night? Probably worth paying for modulating pumps if you are running them nearly all the time. An 80W pump all year costs £98 to run (@14p/unit). That makes it easy to justify a £150 modulating one if it can get the average down to say 40W (pays for itself in 3 years). No idea if those numbers are right but those are the sorts of sums to do.
Maybe you should just buy buy 3 more towels per child (£not much) then each towel would get a couple of weeks to dry, not a few hours. Pay for itself in about 3 weeks I imagine (I assume you do have access to a washing line?). Tumble-driers are something that really should be avoided except in genuine emergencies and maybe the dankest time of the year - if you've arranged life so that every week is an emergency then you're not doing it right.
No, LEDs are not yet cheap (to buy), but then halogens are very expensive to run. But quoting cost-to-buy only is meaningless. You have to compare with running costs to see if it makes (financial) sense (it clearly makes efficiency sense). Right now converting to CFLs is much cheaper and still provides ~70% of the LED savings so that's the way to go for people that don't want to spend much money up front, especially as you can get the bulbs for free.
Some quick payback sums. UK average consumption per year is 780kWh/yr on lighting. (
http://iaeel.org/IAEEL/Archive/Right_Light_Proceedings/Proceedings_body/BOK4/RL4japal.pdf ) that's £84/yr. Let's say it's done with 10 60W bulbs on for 1300hrs each on average, for estimation purposes. Obviously some will be on a great deal and some will only be on occaisionally. That's 420 lumens each.
Do the same lighting with CFL's throughout (costs 10*£3 =£30 to replace), uses ~140kWh, or £20.
Do it with LEDs and it uses ~85kWh or £12. And costs £200 odd for the LEDs.
So CFLs take less than 6 months to pay for themselves. LEDs take 2.8years. That's still very much worthwhile, but if you can't wait 3 years to start saving, just do the CFL thing.