as a black fiol that is heat resistant ther is a product they use in film lighting called black wrap, they use it to control light wrap it ourond to create effects some of it infact most of there lights are very hot 200w upto 20k plus.. it is mat black and great as it disappears as it it as stated mat black hears a link
http://www.filmandvideolighting.com/blstforo12.htmlactually looking at it closer is made from aluminum and is 12in by 50 ft 21 dollar very heat resistant have a look could be useful.

it is really easy to shape about 6 times as thick as baking foil holds its shape even with heat black both sides.
i have some ends of rolls in the shed could test any quick ideas?

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It would work out a little expensive on a large area. On ebay it is about £6 per square metre. Metal roof sheeting is about the same price and it may be possible to find some recycled sheeting.
To test it you would need to put it in a box with plastic cover and blow air through it with a fan and measure the difference in air temperature. For a measurement in kw the speed volume and velocity of the air movement would be needed but for comparison only the temperature difference is needed.
The biggest disadvantage of a makeshift collector is that efficiency would be low on dull days but a big area would make up for this on sunny days. This assumes that the heat can be stored in some way.
I think that the tar system would be a bit messy. Even in Ireland the tar melts on roads on a sunny day. If probably would mean that the collector couldn't be mounted at a steep angle or it it would all go to the bottom. For air heating rather than water there isn't the same problem of concentrating the heat into the smaller water pipes. I am planning on using air to warm the heat store (using clay as the storage medium) but use water pipes to extract the heat because it would be difficult to transfer warm air over a distance. The other advantage of hot air for the collector is that there is no worry about overheating, freezing, leaks etc.